The circular polarization of direct gap emission of Ge is studied in optically excited tensile-strained Ge-on-Si heterostructures as a function of doping and temperature. Owing to the spin-dependent optical selection rules, the radiative recombinations involving strain-split light (cΓ-LH) and heavy hole (cΓ-HH) bands are unambiguously resolved. The fundamental cΓ-LH transition is found to have a low temperature circular polarization degree of about 85%, despite an off-resonance excitation of more than 300 meV. By photoluminescence (PL) measurements and tight-binding calculations we show that this exceptionally high value is due to the characteristic energy dependence of the optically induced electron spin population. Finally, our observation of a direct gap doublet clarifies that the light hole contribution, previously considered to be negligible, can dominate the room temperature PL even at low tensile strain values of ≈0.2%.
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